2-Ethoxy-4-(4-methylphenyl)-6-phenylpyridine-3-carbonitrile

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2-Eth­oxy-4-(4-methyl­phen­yl)-6-phenyl­pyridine-3-carbonitrile

The title compound, C(21)H(18)N(2)O, crystallized with two independent mol-ecules (A and B) in the asymmetric unit. In mol-ecule A, the central pyridine ring forms dihedral angles of 14.55 (13) and 39.14 (12)° with the terminal phenyl and benzene rings, respectively. The latter rings make a dihedral angle of 33.06 (13)° with each other. The corresponding values for mol-ecule B are 26.86 (13), 4...

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2-Amino-4-(4-bromo­phen­yl)-6-ferro­cenyl­pyridine-3-carbonitrile

The title compound, [Fe(C(5)H(5))(C(17)H(11)BrN(3))], was synthesized by the reaction of 4-bromo-benzaldehyde, acetyl-ferrocene and ammonium acetate in an aqueous medium. The crystal packing is stabilized by inter-molecular N-H⋯N hydrogen bonds. The dihedral angles between the phenyl ring and the pyridine and cyclopentadienyl rings are 51.67 (13) and 12.12 (21)°, respectively.

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2-Amino-4-(4-chloro­phen­yl)-6-ferro­cenylpyridine-3-carbonitrile

In the mol-ecule of the title compound, [Fe(C(5)H(5))(C(17)H(11)ClN(3))], the dihedral angles between the two five-membered rings and between the two six-membered rings are 3.28 (4) and 51.33 (4)°, respectively. In the crystal structure, inter-molecular N-H⋯N hydrogen bonds link the mol-ecules into centrosymmetric dimers.

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4 - Chloro - 6 - ethoxy - 2 - ( methylthio ) pyrimidine

4,6-Dichloro-2-(methylthio)pyrimidine (3) reacts with EtONa in EtOH, at ca. 20 ◦C, for 2 h, to give exclusively 4-chloro-6-ethoxy-2-(methylthio)pyrimidine (5) in 89% yield. The latter is presented as a useful multifunctionalised pyrimidine scaffold.

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2-Amino-6-(naphthalen-1-yl)-4-phenyl­pyridine-3-carbonitrile

In the title compound, C(22)H(15)N(3), the naphthyl ring system makes dihedral angles of 67.40 (2) and 59.80 (3)° with the pyridyl and phenyl rings, respectively. In the crystal, the mol-ecules are connected via inter-molecular N-H⋯N hydrogen bonds, forming a three-dimensional network.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2012

ISSN: 1600-5368

DOI: 10.1107/s1600536812032163